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@ARTICLE{Peng:131644,
author = {B. Peng and S. T. Weintraub and C. Coman and S. Ponnaiyan
and R. Sharma$^*$ and B. Tews$^*$ and D. Winter and R.
Ahrends},
title = {{A} {C}omprehensive {H}igh-{R}esolution {T}argeted
{W}orkflow for the {D}eep {P}rofiling of {S}phingolipids.},
journal = {Analytical chemistry},
volume = {89},
number = {22},
issn = {1520-6882},
address = {Columbus, Ohio},
publisher = {American Chemical Society},
reportid = {DKFZ-2017-06276},
pages = {12480 - 12487},
year = {2017},
abstract = {Sphingolipids make up a highly diverse group of
biomolecules that not only are membrane components but also
are involved in various cellular functions such as signaling
and protein sorting. To obtain a quantitative view of the
sphingolipidome, sensitive, accurate, and comprehensive
methods are needed. Here, we present a targeted
reversed-phase liquid chromatography-high-resolution mass
spectrometry-based workflow that significantly increases the
accuracy of measured sphingolipids by resolving nearly
isobaric and isobaric species; this is accomplished by a use
of (i) an optimized extraction procedure, (ii) a segmented
gradient, and (iii) parallel reaction monitoring of a
sphingolipid specific fragmentation pattern. The workflow
was benchmarked against an accepted sphingolipid model
system, the RAW 264.7 cell line, and 61 sphingolipids were
quantified over a dynamic range of 7 orders of magnitude,
with detection limits in the low femtomole per milligram of
protein level, making this workflow an extremely versatile
tool for high-throughput sphingolipidomics.},
cin = {V077},
ddc = {540},
cid = {I:(DE-He78)V077-20160331},
pnm = {319H - Addenda (POF3-319H)},
pid = {G:(DE-HGF)POF3-319H},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:29039908},
doi = {10.1021/acs.analchem.7b03576},
url = {https://inrepo02.dkfz.de/record/131644},
}