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@ARTICLE{Zhang:169400,
author = {S. M. Zhang and D. Rehling and A.-S. Jemth and A. Throup
and N. Landázuri and I. Almlöf and M. Göttmann$^*$ and N.
C. K. Valerie and S. R. Borhade and P. Wakchaure and B. D.
G. Page and M. Desroses and E. J. Homan and M. Scobie and S.
G. Rudd and U. W. Berglund and C. Söderberg-Nauclér and P.
Stenmark and T. Helleday},
title = {{NUDT}15-mediated hydrolysis limits the efficacy of
anti-{HCMV} drug ganciclovir.},
journal = {Cell chemical biology},
volume = {28},
number = {12},
issn = {2451-9456},
address = {Amsterdam},
publisher = {Elsevier},
reportid = {DKFZ-2021-01474},
pages = {1693-1702.e6},
year = {2021},
note = {2021 Dec 16;28(12):1693-1702.e6},
abstract = {Ganciclovir (GCV) is the first-line therapy against human
cytomegalovirus (HCMV), a widespread infection that is
particularly dangerous for immunodeficient individuals.
Closely resembling deoxyguanosine triphosphate, the
tri-phosphorylated metabolite of GCV (GCV-TP) is
preferentially incorporated by the viral DNA polymerase,
thereby terminating chain extension and, eventually, viral
replication. However, the treatment outcome of GCV varies
greatly among individuals, therefore warranting better
understanding of its metabolism. Here we show that NUDT15, a
Nudix hydrolase known to metabolize thiopurine
triphosphates, can similarly hydrolyze GCV-TP through
biochemical studies and co-crystallization of the
NUDT15/GCV-TP complex. More critically, GCV efficacy was
potentiated in HCMV-infected cells following NUDT15
depletion by RNAi or inhibition by an in-house-developed,
nanomolar NUDT15 inhibitor, TH8321, suggesting that
pharmacological targeting of NUDT15 is a possible avenue to
improve existing anti-HCMV regimens. Collectively, the data
further implicate NUDT15 as a broad-spectrum metabolic
regulator of nucleoside analog therapeutics, such as
thiopurines and GCV.},
keywords = {NUDT15 (Other) / Nudix hydrolase (Other) / TH8321 (Other) /
antiherpes (Other) / cytomegalovirus (Other) / ganciclovir
(Other) / high-throughput infectivity assay (Other) /
nucleoside analog drug (Other) / small-molecule inhibitor
(Other)},
cin = {B067},
ddc = {570},
cid = {I:(DE-He78)B067-20160331},
pnm = {312 - Funktionelle und strukturelle Genomforschung
(POF4-312)},
pid = {G:(DE-HGF)POF4-312},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:34192523},
doi = {10.1016/j.chembiol.2021.06.001},
url = {https://inrepo02.dkfz.de/record/169400},
}