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@ARTICLE{Romashov:180979,
      author       = {L. V. Romashov and G. Rukhovich and V. P. Ananikov},
      title        = {{A}nalysis of model {P}d- and {P}t-containing contaminants
                      in aqueous media using {ESI}-{MS} and the fragment
                      partitioning approach},
      journal      = {RSC Advances},
      volume       = {5},
      number       = {130},
      issn         = {2046-2069},
      address      = {London},
      publisher    = {RSC Publishing},
      reportid     = {DKFZ-2022-01704},
      pages        = {107333 - 107339},
      year         = {2015},
      abstract     = {Ubiquitous usage of Pd- and Pt-containing nanoparticles in
                      automotive catalytic converters is an importantpotential
                      threat to the environment. The unavoidable release of
                      transition metal species to the environmentand their contact
                      with water give rise to the poisoning of ecosystems by heavy
                      metal compounds.Electrospray ionization mass spectrometry
                      and the newly-developed fragment partitioning approachshow
                      that a variety of metal species may be formed upon contact
                      of metal salts with water. A series ofmonometallic
                      complexes, homonuclear clusters and heteronuclear clusters
                      of palladium and platinumwere detected and characterized.
                      The study has revealed a critical danger of metal
                      contamination due toeasy formation of transition metal
                      clusters, which may be much more toxic than
                      correspondingmonometallic complexes.},
      ddc          = {540},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1039/C5RA22257E},
      url          = {https://inrepo02.dkfz.de/record/180979},
}