TY  - JOUR
AU  - Wei, Kaiyang
AU  - Nodari, Davide
AU  - Rodríguez-Martínez, Xabier
AU  - Tsetseris, Leonidas
AU  - Nega, Alkmini D
AU  - Dimitrakopoulou-Strauss, Antonia
AU  - Rimmele, Martina
AU  - Hastas, Nikos
AU  - Li, Yijia
AU  - Eisner, Flurin
AU  - Matzapetakis, Manolis
AU  - Martin, Jaime
AU  - Gregoriou, Vasilis G
AU  - Gasparini, Nicola
AU  - Chochos, Christos L
AU  - Panidi, Julianna
TI  - Novel ambipolar polymers for detection beyond 1000 nm with organic phototransistors.
JO  - Materials Horizons
VL  - 13
IS  - 1
SN  - 2051-6347
CY  - Cambridge
PB  - RSC Publ.
M1  - DKFZ-2025-02074
SP  - 464–472
PY  - 2026
N1  - Mater. Horiz., 2026, 13, 464–472
AB  - Organic phototransistors (OPTs) hold significant promise for cost-effective, flexible optoelectronic applications, particularly in Shortwave-Infrared (SWIR) detection, which is crucial for applications such as health monitoring, communications, and artificial vision. Traditional OPTs often rely on unipolar materials, limiting their efficiency by utilizing only one type of charge carrier. In contrast, ambipolar organic semiconductors (OSCs), transporting both electrons and holes, can fully harness photogenerated carriers, thereby enhancing device performance. Here, high-performance, solution-processed ambipolar single-component SWIR OPTs are demonstrated by fine-tuning the number of fused thiophene rings in donor-acceptor (D-A) conjugated polymers utilizing thiadiazoloquinoxaline-unit (TQ) as the electron-deficient unit. Through systematic polymer characterizations and optoelectronic device characterizations it was revealed that three fused thiophene rings (TQ-T3) delivered ambipolar NIR phototransistors with well-balanced hole and electron mobilities of 0.03 and 0.02 cm2 V-1 s-1 and the highest reported specific detectivity of 2 × 108 Jones (at 1100 nm), with external quantum efficiency of 1400
LB  - PUB:(DE-HGF)16
C6  - pmid:41065342
DO  - DOI:10.1039/D5MH01486G
UR  - https://inrepo02.dkfz.de/record/305228
ER  -