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@ARTICLE{Safian:130461,
author = {M. F. Safian$^*$ and N. Zinn$^*$ and J. Seidler$^*$ and W.
D. Lehmann$^*$},
title = {{M}icroquantification of phospholipid classes by stable
isotope dilution and nano{ESI} mass spectrometry.},
journal = {Fresenius' journal of analytical chemistry},
volume = {408},
number = {27},
issn = {1618-2650},
address = {Berlin},
publisher = {Springer56756},
reportid = {DKFZ-2017-05540},
pages = {7663 - 7667},
year = {2016},
abstract = {A new method for microquantification of phospholipid
classes by nanoelectrospray mass spectrometry and stable
isotope dilution is presented. The method covers the sum of
phosphatidylcholine and sphingomyelin and in addition
selectively quantifies phosphatidylethanolamine,
phosphatidylserine, and phosphatidylinositol. A phospholipid
class is quantified together with its corresponding
lyso-species due to the presence of a common head group.
Phospholipids are extracted from tissue lysates, hydrolysed
by hydrofluoric acid, and the liberated polar head groups
choline, ethanolamine, serine, and inositol are quantified
by nanoelectrospray mass spectrometry using
deuterium-labeled analogs of the head groups as internal
standards. The method is applied to tissue samples of a
gastrointestinal tumor and of corresponding non-affected
control tissue. In the tumor sample, the abovementioned
phospholipids were found at roughly threefold elevated
concentrations with a virtually unaltered relative abundance
profile.},
cin = {W160},
ddc = {540},
cid = {I:(DE-He78)W160-20160331},
pnm = {312 - Functional and structural genomics (POF3-312)},
pid = {G:(DE-HGF)POF3-312},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:27515797},
doi = {10.1007/s00216-016-9859-3},
url = {https://inrepo02.dkfz.de/record/130461},
}